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Dendritic Effect in Polymer-Supported Catalysis of the Intramolecular Pauson—Khand Reaction.

✍ Scribed by Adi Dahan; Moshe Portnoy

Publisher
John Wiley and Sons
Year
2003
Weight
99 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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Absfrrrct 6-Cyclopropylidenel-hexynes like 2, e. g. prepared via palladium(O)-catalyzed substitution of l-ethenyl cyclopropyl sulfonates 1, undergo an intramolecular huson-Khand reaction both efficiently and regioselectively.