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First evidence for the existence of intramolecular carbon-hydrogen-carbon hydrogen bonds: carbanions of [1.1]ferrocenophane, 1-methyl-[1.1]ferrocenophane, and 1,12-dimethyl-[1.1]ferrocenophane

✍ Scribed by Mueller-Westerhoff, Ulrich T.; Nazzal, Adel; Proessdorf, Wolfram


Book ID
120358148
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
597 KB
Volume
103
Category
Article
ISSN
0002-7863

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The Stevens and related rearrangements1 have been a subject of great current interest particularly with respect to the mechanisms for these anionic migrations. The N to N migration of aminimines (e.g. II -f III) known as the Wawzonek rearrangement, 2 has been investigated in our laboratories. 3 The