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The First 1,3-Distanna-2-platina-[3] ferrocenophane and the Pt0-Catalyzed Addition of 1, 1, 2, 2,-Tetramethyl-1, 2-distanna-[2] ferrocenophane to CC Bonds

✍ Scribed by Prof. Dr. Max Herberhold; Dipl.-Chem. Udo Steffl; Dr. Wolfgang Milius; Prof. Dr. Bernd Wrackmeyer


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
429 KB
Volume
36
Category
Article
ISSN
0044-8249

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Eine Zwischenstufe der metallkatalysierten Distannylierung von Alkinen, der Komplex 1, wurde erstmals — durch Röntgenstrukturanalyse und Multikern‐NMR‐Spektroskopie — vollständig charakterisiert. Die[4]Ferrocenophane 2 lassen sich direkt durch Addition von 1,2‐Bis(dimethylstanna)[2]ferrocenophan an

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2, ferrocenophane (1) was prepared by the reaction of 1,1'-bis(dimethylstannyl)ferrocene (3) with bis(diethylamino)dimethylstannane. The molecular structure of 1 was determined by X-ray crystallography. The monoclinic unit cell (space group P2 1 /c; a = 18.659(4), b = 17.311(3), c = 13.719(3) A Ê ;

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