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X-ray crystal structure of 1,1-dimethyl-1-phenacylhydrazinium bromide. Evidence for intramolecular hydrogen bonding

โœ Scribed by Leslie Lessinger; Mary K. Killoran; Jean-Pierre Anselme; Thomas N. Margulis


Book ID
104235530
Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
197 KB
Volume
18
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


The Stevens and related rearrangements1 have been a subject of great current interest particularly with respect to the mechanisms for these anionic migrations. The N to N migration of aminimines (e.g. II -f III) known as the Wawzonek rearrangement, 2 has been investigated in our laboratories. 3 The con-


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The crystal structure of N-(l-octyl)-o-talonamide [space group P2,2,21, a = 914.0(2), b = 581.4(l), c =6257(l) pm] shows two independent molecules in the asymmetric unit. The oligomethylene chains of both molecules are extended. The talonic acid moieties have a gauche-bend along C-l-C-2-C-3-C-4 ther