Ferrocenylphosphine complexes of gold bromide
✍ Scribed by A. N. Nesmeyanov; É. G. Perevalova; O. B. Afanasova; K. I. Grandberg
- Book ID
- 112438817
- Publisher
- Springer
- Year
- 1977
- Tongue
- English
- Weight
- 227 KB
- Volume
- 26
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Aldol reaction of N,N-dialkyl-a-isocyanoacetamides with primary alkyl aldehydes in the presence of 0.5-l mol% OF a chiral (aminoalkyl)ferrocenylphosphine-gold(I) catalyst proceeded with high enantio-and diastereoselectivity to give trans-5-alkyl-2-oxazoline-4-carboxamides of up to 98.6% ee, which we
summsry: Asymmetric aldol reaction of a-ketoesters (RCOCCCMe: R = Me, i-Bu, ph) with methyl isocyanoacetate or N,N-dimethyl-a-isocyanoacetamide in the presence of 1 molX of a chiral (arinoalkyl)ferrocenylphosphine-gold(I) catalyst proceeded with high enantioselectivity to give corresponding oxazolin
swmnary : Optically active norbornyl and l-phenylethyl alcohols and bromides were obtained, res- pectively, from norbornyl-and l-phenylethylpentafluorosilicates which were prepared by asymmetric hydrosilylation of norbornene and styrene with trichlorosilane catalyzed by a chiral ferrocenylphosphine-