summsry: Asymmetric aldol reaction of a-ketoesters (RCOCCCMe: R = Me, i-Bu, ph) with methyl isocyanoacetate or N,N-dimethyl-a-isocyanoacetamide in the presence of 1 molX of a chiral (arinoalkyl)ferrocenylphosphine-gold(I) catalyst proceeded with high enantioselectivity to give corresponding oxazolin
Catalytic asymmetric aldol reaction: reaction of aldehydes with isocyanoacetate catalyzed by a chiral ferrocenylphosphine-gold(I) complex
โ Scribed by Ito, Yoshihiko.; Sawamura, Masaya.; Hayashi, Tamio.
- Book ID
- 120523122
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 286 KB
- Volume
- 108
- Category
- Article
- ISSN
- 0002-7863
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