Ferrocene compounds. XXX. Methyl 1′-acetamidoferrocene-1-carboxylate
✍ Scribed by Pavlović, Gordana ;Barišić, Lidija ;Rapić, Vladimir ;Leban, Ivan
- Publisher
- International Union of Crystallography
- Year
- 2001
- Tongue
- English
- Weight
- 276 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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Chiral oxazolinyl-modi®ed ferrocenecarboxylic acid, (S,S p )-[Fe{ 5 -C 5 H 3 (CO 2 H-1)(C 6 H 10 NO-2)}( 5 -C 5 H 5 )] or [Fe(C 5 H 5 )-(C 12 H 14 NO 3 )], crystallizes as a molecular compound, featuring an intramolecular OÐHÁ Á ÁN hydrogen bond between the carboxyl hydroxy group and oxazoline N ato
The title compound, [Fe(C 5 H 5 )(C 14 H 16 N)], has been synthesized to act as a precursor to ferrocenylaminophosphines. The dihedral angle between the substituted cyclopentadienyl plane and the plane of the phenyl ring is 65.0 (2) .