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Far-UV and photoelectron spectra of 1,3,5-trifluorobenzene

✍ Scribed by R. Gilbert; P. Sauvageau; C. Sandorfy

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 526 KB
Volume: 17
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)85081-4

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✦ Synopsis

Ihe photoelec:ror, and vacuum-dltraviolet absorption spectra of 1,3,5trifluor~benzenc id its fully deuterated analog were measured. The two lowest ion-k&on potentials correspond to the r levels. We find twd Rydberg series converging to the First IP and one converging to the second IP. The assignments are confiird by the similarities between the vibrational fine smxtures of the ahotoelectron and the related Rydberg bands, 'These fine s:ructUres . exhibit signiIicant differences with respect to benzene,

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