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The magnetic susceptibility anisotropy of benzene, 1,3,5-trifluorobenzene and hexafluorobenzene

โœ Scribed by M.P. Bogaard; A.D. Buckingham; M.G. Corfield; D.A. Dunmur; A.H. White

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
193 KB
Volume
12
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The magnetic susceptibility anisotropy of benzene, 1,3,5trifluorobenzene and hexafluorobenzene is obtained from measurements of the Cotton--Mouton effect on the gases. Substitution of fluorine for hydrogan results in a decrease in the magnetic susceptibility anisotropy.

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## An inrerpreistion of certain features in the vibrational pattcm of the 11.5 to 13.0 eV photoelectron spectrum of bcnzene in terms of a Jahn-Teller effect Is presented. This supports Lindholm's orbiral assignrncnt of the ionization processes in this'region. A change iri the assignment of some of