The magnetic susceptibility anisotropy of benzene, 1,3,5trifluorobenzene and hexafluorobenzene is obtained from measurements of the Cotton--Mouton effect on the gases. Substitution of fluorine for hydrogan results in a decrease in the magnetic susceptibility anisotropy.
The orbital interpretation of the photoelectron spectrum of benzene, 1,3,5-trifluorobenzene and hexafluorobenzene
β Scribed by W.C. Price; A.W. Potts; T.A. Williams
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 285 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
An inrerpreistion
of certain features in the vibrational pattcm of the 11.5 to 13.0 eV photoelectron spectrum of bcnzene in terms of a Jahn-Teller effect Is presented. This supports Lindholm's orbiral assignrncnt of the ionization processes in this'region. A change iri the assignment of some of the hihcr systems in the photoelectron spectra of 1,3,5,-trifluoiobcn-
π SIMILAR VOLUMES
The inner-valence (20-36 eV) photoelectron spectrum of N, is interpreted by comparing with various spectra (such as absorption, N+-yield, fluorescence-yield, and core-level photoelectron spectra). This comparative study conflrms the previous assignments on the bands at 25.3 and 29.0 eV and clarifies
The angular distribution of photoelectrons ejected from benzene using 21.22 eV radiation has been measured and the results applied to the analysis of the ionization bands. ## * Research sponsored by the l&S:'Atomic Energy Commit+ i-ion under contract with the Union Carbide Corporati?n.