𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Facile Synthesis of α-Substituted Acrylate Esters

✍ Scribed by Hin, Bunda; Majer, Pavel; Tsukamoto, Takashi

Book ID
120400487
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
171 KB
Volume
67
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Facile synthesis of β-alkyl-substituted
Facile synthesis of β-alkyl-substituted esters from α,β-unsaturated aldehydes
✍ Tsujiaki Hata; Masashi Nakajima; Mitsuo Sekine 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 210 KB

8-Alkyl-substituted carboxylates were synthesized in good yields from U,B-unsaturated aldehydes by using the 1:l carbonyl adducts with diethyl bis(trimethylsily1) phosphite. Recently, several studies on acyl anion equivalents utilizing carbonyl insertion reactions have appeared. 2 It has been report

A Stereoselective Synthesis of α-(1-Hydr
A Stereoselective Synthesis of α-(1-Hydroxyalkyl)-β-Substituted Acrylic Acid Esters
✍ Taı̈cir Ben Ayed; Jean Villiéras; Hassen Amri 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 106 KB

Nucleophilic substitution of vinylic iodide of methyl 2-(1-hydroxyalkyl)-3-iodo prop-2-enoates 8 in the presence of magnesium dialkyl cuprates generated in situ provided a stereoselective methodology for the synthesis of infrequent b-substituted Baylis-Hillman products.

A facile stereospecific synthesis of α-h
A facile stereospecific synthesis of α-hydrazino esters
✍ Umut Oguz; Garett G. Guilbeau; Mark L. McLaughlin 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 68 KB

A convenient route to make a-hydrazino esters from their corresponding a-amino esters is reported. A key step is selective nitrosamine reduction using activated Zn, conc. HCl, and methanol at low temperatures giving nearly quantitative yields of the pure a-hydrazino esters