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Facile Synthesis of Steroidal Phenyl Ketones via Homogeneous Catalytic Carbonylation

✍ Scribed by Rita Skoda-Földes; Zoltán Székvölgyi; László Kollár; Zoltán Berente; Judit Horváth; Zoltán Tuba

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
85 KB
Volume
56
Category
Article
ISSN
0040-4020

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✦ Synopsis

AbstractÐSteroidal phenyl ketones were synthesised in high yields by palladium-catalysed carbonylation reactions of 17-iodo-androst-16-ene derivatives in the presence of NaBPh 4 under mild reaction conditions. Alkenyl bromides or enol tri¯ates gave lower yields in the same reaction.

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