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Facile synthesis of a novel sapphyrin and its rhodium(I) complex

✍ Scribed by Liliya Simkhovich; Shira Rosenberg; Zeev Gross

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
77 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

The rhodium(I) complex of the novel meso-pentafluorophenylsapphyrin is obtained in very high yield by oxidation of the corresponding open-chain pentapyrrole by iodine or oxygen, followed by metallation.

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