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A Novel Five-Coordinate Rhodium(I) Complex

✍ Scribed by Igor O. Koshevoy; Olga V. Sizova; Sergey P. Tunik; Alan Lough; Anthony J. Poë

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 98 KB
Volume: 2005
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200500444

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## Abstract Five‐coordinate complexes have been prepared, of the general formulae [CoX(L'L~3~)]^+^ and [RhX(L'L~3~)], where X = halogen and L'L~3~ = a quadridentate tripod‐like ligand containing various Group V donor atom sets. The electronic spectra and magnetism of the cobalt(II) series can be in