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Facile synthesis and characterization of μ-chloro, azido, thiocyanato bridged cyclometallated Pd(II) containing Schiff-base ligands

✍ Scribed by Yuchun Jiang; Yonglin Guo; Xia Zhu; Dandan Song; Yu Wang; Ximing Song; Francis Verpoort; Xiaohong Chang


Book ID
113642164
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
755 KB
Volume
376
Category
Article
ISSN
0020-1693

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## Abstract The copper coordination chemistry of a new imidazolidine‐based doubly bridging μ‐bis(tetradentate) ligand, H~3~mhbai is studied. A new family of pentacoordinate dinuclear complexes of formula [Cu^II^~2~(‐mhbai)(‐X)]·2 H~2~O (1–4) [X = OAc, NO~3~, Cl, S~2~COMe], where H~3~mhbai stands fo