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Synthesis, Crystal Structure, and Magnetic Properties of a Very Rare Double μ-1,1-Azido- and a μ-1,1-(OMe)-Bridged FeIII Dimer Containing a N,N,O-Donor Tridentate Schiff Base Ligand

✍ Scribed by Subrata Naiya; Michael G. B. Drew; Carmen Diaz; Joan Ribas; Ashutosh Ghosh

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
462 KB
Volume
2011
Category
Article
ISSN
1434-1948

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μ-η1:η1-N,N'-Imidazolidine-Bridged Dicop
μ-η1:η1-N,N'-Imidazolidine-Bridged Dicopper(II/III) Complexes of a New Dinucleating μ-Bis(tetradentate) Schiff Base Ligand: Synthesis, Structural Characterization, 1H NMR Spectroscopy, and Magnetic Coupling
✍ Manindranath Bera; Wing Tak Wong; Guillem Aromí; Debashis Ray 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB

## Abstract The copper coordination chemistry of a new imidazolidine‐based doubly bridging μ‐bis(tetradentate) ligand, H~3~mhbai is studied. A new family of pentacoordinate dinuclear complexes of formula [Cu^II^~2~(‐mhbai)(‐X)]·2 H~2~O (1–4) [X = OAc, NO~3~, Cl, S~2~COMe], where H~3~mhbai stands fo