The laser-induced decomposition of a solid azido polymer (GAP) is reported. A TEA CO 2 laser (tunable in the 920-1080 cm -1 range) is used and the dissociation yield is shown to correlate with the one photon absorption spectrum, although about 15 photons per molecule are required to break the weakes
Facile infrared laser-induced decomposition of triethyl phosphite
β Scribed by C.N. Merrow; N.S. Nogar
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 591 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The pulsed CO* laser photolyss of tnethyl phosptite, P(OC2Hs)s 1s reported. Ummolecular decomposition produces PO (OCz Hs )z and C2Hs. Sequential photo11 SIS and/or subsequent bunolecular reactton yields the observed end products and accounts for lununescence from PO, (PO)2, Cz, HP0 and OH The facile nature of tti process IS discussed, and mechamsms suggested
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