✦ LIBER ✦

Photosensitized decomposition of hydrocarbons by infrared-laser-induced energy transfers

✍ Scribed by H. Pazendeh; C. Marsal; F. Lempereur; J. Tardieu de Maleissye

Publisher: John Wiley and Sons
Year: 1979
Tongue: English
Weight: 518 KB
Volume: 11
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550110606

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✦ Synopsis

Abstract

Using the technique of CO~2~ laser photosensitized decomposition, ethane and propane decomposition was investigated in relation to energy transfer from an SF~6~ photosensitizer to the hydrocarbon. The end products appearing in the course of irradiation are similar to those formed during classical thermal pyrolysis. The energy transfer from SF~6~ to the hydrocarbon is closely related to hydrocarbon decomposition. A similar overall kinetic behavior for the two alcanes allows the use of a general diffusional kinetic treatment, provided pressure, intensity, and duration of irradiation are well defined.

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