✦ LIBER ✦
Infrared multiple-photon decomposition of Fe(CO)5 induced by an infrared p-H2 raman laser
✍ Scribed by Tetsuro Majima; Hideo Tashiro; Katsumi Midorikawa; Michio Takami
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 331 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
InCnred mulIiple-pholon decomposiIion (IRMPD) or Fe(CO), induced by an IR p-H1 Raman laser has been srudied. The decomposirion erficienrly occurs wirh the irmdiaGon of unrocused laser beam BL 616.1 cm-'. The decomposition producls are mainly CO and mekxllic iron. In IRMPD or a mixture or Fc(CO), and 1-butrnc or I-pcn~cnc. isomeriwtion of these olclins hy active inlenncdinles is not observed. The resuhs are explained by Tas1 sequenlial decarbonylmion or Fe(CO)5 in highly excited vibraGonal SLZWZ.