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Facile and Highly Stereoselective One-Pot Synthesis of Either (E)- or (Z)-Nitro Alkenes

✍ Scribed by Fioravanti, Stefania; Pellacani, Lucio; Tardella, Paolo A.; Vergari, Maria Cecilia


Book ID
115467213
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
53 KB
Volume
10
Category
Article
ISSN
1523-7060

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Stereoselective synthesis of either E- o
✍ Nadine HΓ©naff; Sarah K Stewart; Andrew Whiting πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 127 KB

Reaction of alkynes with ICI and an iodide source results in the stereoselective formation of diiodoalkenes in moderate to high yield. At r.t., the reaction is stereospecific, resulting in the formation of E-diiodoalkenes, however lowering the temperature mad using a more soluble iodide som'ee resul