Convenient one-pot synthesis of functionalized unsymmetrical (Z) or (E)-enediynes from (Z) or (E)-1,2-dichloroethylene. An efficient route to (Z,Z,Z) and (Z,E,Z)-trienes
✍ Scribed by Mouâd Alami; Benoit Crousse; Gérard Linstrumelle
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 135 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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## Abstract (__Z__)‐2‐Butenyl‐dimethoxyborane adds smoothly to propanal and benzaldehyde to afford the homoallyl alcohols (__R__\*,__R__\*)‐**1** and (__R__\*,__R__\*)‐**2**, In contrast (__E__)‐2‐butenyl‐dimethoxyborane leads to adducts having the (__R__\*,__S__\*)‐configuration. Dimethoxy‐(__Z__)