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ChemInform Abstract: Efficient and Stereoselective One-Pot Syntheses of Diethyl (Z)- or (E)- 1-Alkylidene-3-oxobutylphosphonates.

✍ Scribed by A. MOHAMED-HACHI; E. ABOUT-JAUDET; J.-C. COMBRET; N. COLLIGNON


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereoselective One
✍ Susumu Horii; Isao Ishimaru; Yutaka Ukaji; Katsuhiko Inomata πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 41 KB

## Abstract The rearrangement of allylic sulfones induced by the successive treatment with KOtBu and LDA affords the corresponding dienyl alcohols with high selectivity for the formation of the respective (Z)‐isomer, due to a syn‐effect in the elimination step.