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Stereoselective synthesis of either E- or Z-diiodoalkenes from alkynes using ICI and iodide

✍ Scribed by Nadine Hénaff; Sarah K Stewart; Andrew Whiting

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
127 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reaction of alkynes with ICI and an iodide source results in the stereoselective formation of diiodoalkenes in moderate to high yield. At r.t., the reaction is stereospecific, resulting in the formation of E-diiodoalkenes, however lowering the temperature mad using a more soluble iodide som'ee results in a stereoselective formation of the Z-diiodoalkenes.

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