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Facile [3,3] rearrangement of substituted 3α-& 5α-hydroxytricyclo[5.2.1.02,6]decadienes

✍ Scribed by Suresh Chander Suri; Stephen L. Rodgers; Walter J. Lauderdale

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
260 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis

Functionaiized tricy~10(5.2.1.O2.$1~~~ systems are proved to be very versatile synthons for the synthesis of cyclopentanoid natural products3 and caged compoundk. Because of their rigidity, chemical transformations on these systems occur with complete stenzo-and/or ngio-conmA. The oxo-derivatives of tricyclodecadienes I& 2 undergo Cope reammgement to furnish thermodynamically rmxe stable enone systems 9 & 4 nqectively under elecuophilic~ 1 X=H

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