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Facially Selective and Regioselective Carbometalation of Cyclopropenes by Aryl Grignard Reagents

โœ Scribed by Yan, Ni; Liu, Xiaozhong; Fox, Joseph M.


Book ID
125986945
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
148 KB
Volume
73
Category
Article
ISSN
0022-3263

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Selective mono-arylation and -alkylation
โœ Marcello Tiecco; Lorenzo Testaferri; Marco Tingoli; Donatella Chianelli; Ernest ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 210 KB

Chlorophenyl alkyl sulfides are mono-arylated and -alkylated selectively with Grignard reagents, in the presence of Ni(PPh3)2C12, to give aryl-and alkyl-phenyl alkyl sulfides.