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Extension of the Criegee Rearrangement: Synthesis of Enol Ethers from Secondary Allylic Hydroperoxides

โœ Scribed by Goodman, Richard M.; Kishi, Yoshito

Book ID
118209527
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
392 KB
Volume
59
Category
Article
ISSN
0022-3263

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Allyloxy ketone enol ether-claisen rearr
Allyloxy ketone enol ether-claisen rearrangement. regiospecific synthesis of allyl ketones from allyl alcohols
โœ Joseph L.C. Kachinski; Robert G. Salomon ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

Claisen rearrangement of ally1 vinyl ethers is an important general method of carboncarbon bond formation for synthesis of y,b-unsaturated aldehydes and ketones. 1 Syntheses of y,b-unsaturated esters and amides are similarly achieved by rearrangements of 2-alkoxy and 2amino-3-oxa-1,5-hexadienes.