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Allyloxy ketone enol ether-claisen rearrangement. regiospecific synthesis of allyl ketones from allyl alcohols

✍ Scribed by Joseph L.C. Kachinski; Robert G. Salomon

Publisher: Elsevier Science
Year: 1977
Tongue: French
Weight: 212 KB
Volume: 18
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)83205-6

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✦ Synopsis

Claisen rearrangement of ally1 vinyl ethers is an important general method of carboncarbon bond formation for synthesis of y,b-unsaturated aldehydes and ketones. 1 Syntheses of y,b-unsaturated esters and amides are similarly achieved by rearrangements of 2-alkoxy and 2amino-3-oxa-1,5-hexadienes.

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