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Stereoselective Synthesis of Allyl Vinyl Ethers from Silyl Enol Ethers

โœ Scribed by Maeda, Katsuya; Shinokubo, Hiroshi; Oshima, Koichiro; Utimoto, Kiitiro


Book ID
126091997
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
182 KB
Volume
61
Category
Article
ISSN
0022-3263

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Novel peparation of silyl enol ethers fr
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A novel synthetic method for silyl enol ethers from ally1 alcohols was developed using ruthenium hydride catalyst.

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While regiochemical aspects of enolate chemistry have been studied extensively, 1 virtually no attention has been paid until recently to geometry of the double bond of enolate anions.