𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Extension of BEBO method for the estimation of activation energies of intraradical 1,2-hydrogen shift reactions

✍ Scribed by L. Valko; P. Šimon


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
867 KB
Volume
99
Category
Article
ISSN
0301-0104

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


A simple empirical method for the estima
✍ Ze'ev B. Alfassi; Sidney W. Benson 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 633 KB

## Abstract Several new empirical methods are presented for the prediction of activation energies __E__ of the metathetical transfer reaction of single bonded atoms in radical‐molecule reactions of the type A· + BC → AB + C· The methods assign additive contributions to __E__ for the endgroups A· an

Estimation of the R-H bond energy from t
✍ E. T. Denisov; L. N. Denisova 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 313 KB

Since the activation energy for the reaction R H + 0 2 -+ R . + HO; is very close to its endothermicity, the R-H bond energy can be calculated from the activation energy for free radical formation by the reaction R H + 0 2 . The relation between Ei and QR-H was found empirically after measuring Ei b

Evidence for a 1,2 Shift of a Hydrogen A
✍ Meinrad Kunz; Jànos Rétey 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 100 KB

An excellent substrate of methylmalonyl-CoA mutase, methylmalonyl-carba-(dethia) coenzyme A (methylmalonyl-CH(2)-CoA), was synthesized by a chemoenzymatic method and its alpha-proton was exchanged with deuterium by long-term incubation in deuterium oxide at pH 6.9. After addition of highly purified