A gel point method for the estimation of overall apparent activation energies of polymerization
β Scribed by L. J. Gough; I. T. Smith
- Publisher
- John Wiley and Sons
- Year
- 1960
- Tongue
- English
- Weight
- 236 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0021-8995
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A systematic quantitative method for the selection of models for the highconversion free radical polymerization exhibiting gel and glass effects has been developed. Four representative models were selected from the literature and were compared on the basis of the same experimental data. All models d
## Abstract The conventional linear integral isoconversional methods may lead to important errors in the determination of the activation energy when the significant variation of the activation energy with the conversion degree occurs. Vyazovkin proposed an advanced nonlinear isoconversional method,