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Extension of the bebo method for the calculation of activation energies of intraradical 1,3-, 1,4- and 1,5-hydrogen shift reactions

✍ Scribed by P. Šimon; L. Valko


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
653 KB
Volume
117
Category
Article
ISSN
0301-0104

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The rate constants for the 1,3-and 1,Mgmatropic hydrogen shifts of the phot&Fries rearranged intermediates of phenyl acetate produced by laser flash photolysis at 266 nm were directly measured in several solvents. The rate constant for the 1,3hydrogen shift (3.6 s-l) was faster than that for the l&s