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Experimental Study of the Reaction between Vinyl and Methyl Radicals in the Gas Phase. Temperature and Pressure Dependence of Overall Rate Constants and Product Yields

✍ Scribed by Stoliarov, Stanislav I.; Knyazev, Vadim D.; Slagle, Irene R.


Book ID
126082673
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
177 KB
Volume
104
Category
Article
ISSN
1089-5639

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The kinetics of the reaction CHs + OH ( +M ) -CH,OH( + M ) was studied in the temperature range 283-373 K and in the pressure range 85-1000 mbar SF, by pulse radiolysis combined with UV absorption spectroscopy. The methyl and hydroxyl radical decays were followed by monitoring the transient UV absor