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Direct Time-Resolved Study of the Gas-Phase Reactions of Germylene with Ethyl- and Diethylgermane: Absolute Rate Constants, Temperature Dependences, and Mechanism

✍ Scribed by Becerra, Rosa; Boganov, Sergey E.; Egorov, Mikhail P.; Krylova, Irina V.; Nefedov, Oleg M.; Walsh, Robin


Book ID
126223280
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
88 KB
Volume
111
Category
Article
ISSN
1089-5639

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Temperature-dependent rate coefficients
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## Abstract The rate coefficient for the gas‐phase reaction of chlorine atoms with acetone was determined as a function of temperature (273–363 K) and pressure (0.002–700 Torr) using complementary absolute and relative rate methods. Absolute rate measurements were performed at the low‐pressure regi