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Experimental and Theoretical Studies of Homoleptic Tellurium Cyanides Te(CN)x: Crystal Structure of Te(CN)2

✍ Scribed by Thomas M. Klapötke; Burkhard Krumm; Juan Carlos Gálvez-Ruiz; Heinrich Nöth; Ingo Schwab

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 198 KB
Volume: 2004
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200400763

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✦ Synopsis

The labile tellurium cyanide species Te(CN) 2 and Te(CN) 4 have been prepared by treatment of tellurium(IV) tetrahalides with cyanide. Both are thermosensitive solids and, in addition, the tetracyanide was found to be pyrophoric. The crystal structure of Te(CN) 2 has been determined. The struc- [ ‡] X-ray structure analysis.

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