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Experimental and Theoretical Studies of Homoleptic Tellurium Cyanides Te(CN)x: Crystal Structure of Te(CN)2.

✍ Scribed by Thomas M. Klapoetke; Burkhard Krumm; Juan Carlos Galvez-Ruiz; Heinrich Noeth; Ingo Schwab


Publisher
John Wiley and Sons
Year
2005
Weight
15 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Experimental and Theoretical Studies of
✍ Thomas M. Klapötke; Burkhard Krumm; Juan Carlos Gálvez-Ruiz; Heinrich Nöth; Ingo 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 198 KB

The labile tellurium cyanide species Te(CN) 2 and Te(CN) 4 have been prepared by treatment of tellurium(IV) tetrahalides with cyanide. Both are thermosensitive solids and, in addition, the tetracyanide was found to be pyrophoric. The crystal structure of Te(CN) 2 has been determined. The struc- [ ‡]