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Experimental and ab initio evidence for preferred syn-conformation of thionyl amines, , X = H, CH3, and C6H5

✍ Scribed by B. Bak; H. Svanholt; C. Larsen

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
318 KB
Volume
36
Category
Article
ISSN
0022-2860

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S i x new complexes o f the t y p e [C5H5Mo(CO)2NN\*]PF6 have been p r e p a r e d by t r e a tment o f C5H5Mo(C0)3C1 w i t h t h e S c h i f f b a s e s NN\*, d e r i v e d from 2 -a c e t y l p y r i d i n e o r 2-benzoyl p y r i d i n e and c h i r a l amines ( C 6 H 5 ) , and (CH3) ( C 2 H 5 ) .