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Preparation of Diamidochloro(cyclopentadienyl)titanium Derivatives as Pre-Catalysts for Olefin Polymerization − X-ray Molecular Structure of [Ti(η5-C5H5){1,2-C6H4(NCH2CH2CH3)2}Cl] and [Ti{η5-C5H4(SiMe3)}{1,2-C6H4(NCH2CH2CH3)2}Cl]

✍ Scribed by Vanessa Tabernero; Tomás Cuenca; Eberhardt Herdtweck


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
184 KB
Volume
2004
Category
Article
ISSN
1434-1948

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## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3