Expeditive Synthesis of Homochiral Fused Tri- and Tetrazoles—Piperazines from β-Amino Alcohols.
✍ Scribed by Francois Couty; Francois Durrat; Damien Prim
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 158 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
aminoacylsilanes 1 and 13 and of the N-Ts-aminoacylsilane 5 with allyltrimethylsilane. Lower de values were obtained A practical route is described for the synthesis of enantiopure β-and γ-amino alcohols with two stereocenters, starting from in the Sc(OTf) 3 -catalyzed allylation of 5 with tetraally
Synthesis of Enantiopure β-and γ-Amino Alcohols from Homochiral α-and β-Aminoacylsilanes as Stable Synthetic Equivalents of α-and β-Amino Aldehydes. -The stereoselectivity is strongly dependent on both the type of protecting group and reagents used. -(BONINI, BIANCA