Quantum mechanical calculations at the MP2/6-31 G(d) level are reported for the silaguanidinium cation Si(NH,): (1) and derivatives thereof. The equilibrium structure 1 a has D, symmetry with planar amino groups rotated out of the SIN, plane by 19.6". The Si-N bond length of 1 a (1.658 A) is interme
Existence of the Halocarbonyl and Trifluoromethyl Cations in the Condensed Phase
โ Scribed by Christe, K. O.; Hoge, B.; Boatz, J. A.; Prakash, G. K. S.; Olah, G. A.; Sheehy, J. A.
- Book ID
- 126177097
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 312 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0020-1669
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