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Spectroscopic Observation of the Formyl Cation in a Condensed Phase

โœ Scribed by de Rege, P. J.

Book ID
121157752
Publisher
American Association for the Advancement of Science
Year
1997
Tongue
English
Weight
484 KB
Volume
276
Category
Article
ISSN
0036-8075

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The Silaguanidinium Cation and the Searc
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โœ Ulrich Pidun; Martin Stahl; Gernot Frenking ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 871 KB

Quantum mechanical calculations at the MP2/6-31 G(d) level are reported for the silaguanidinium cation Si(NH,): (1) and derivatives thereof. The equilibrium structure 1 a has D, symmetry with planar amino groups rotated out of the SIN, plane by 19.6". The Si-N bond length of 1 a (1.658 A) is interme