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Excited state dynamics of the11BO2 free radical

✍ Scribed by Lu Cheng-zai; Michael A.A. Clyne; Ian P. Llewellyn

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 249 KB
Volume: 104
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85312-9

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✦ Synopsis

The excitation spectrum of the double-headed OO'O-00'0 band of B02(AZrIn-X 2~g) wasrecorded by LIF. Special attention was paid to determine the dependence of the radiative lifetime of (OO"O) A 2~ state with J and the quenching by bath gases N2. Ar, 02. The determinations of fluorescence decay were made in real time. The mean radiative lifetime 7, of the A2~3,2(0000) state of l1 BOz was determined to be 91 * 4 ns (1~).

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