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Excited-state absorption in a terpyridyl platinum(II) pentynyl complex

✍ Scribed by Pritchett, Timothy M.; Sun, Wenfang; Guo, Fengqi; Zhang, Bingguang; Ferry, Michael J.; Rogers-Haley, Joy E.; Shensky, William; Mott, Andrew G.


Book ID
115430684
Publisher
Optical Society of America
Year
2008
Tongue
English
Weight
291 KB
Volume
33
Category
Article
ISSN
0146-9592

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## Abstract The platinum(II) terpyridyl acetylide complex [Pt(terpy)(Cο£½CR)]ClO~4~ (terpy=2,2β€² : 6β€²2″‐terpyridine, R=CH~2~CH~2~CH~3~) (1) was incorporated into Nafion membranes. At high loading the dry membranes exhibit intense photoluminescence with Ξ»~max~ at 707 nm from the ^3^MMLCT state. which w