Tuning the lowest excited-states of platinum (II) terpyridyl acetylide complex bearing azacrown moiety: Stimulated by transition metal ions

Switch of the Lowest Excited-States of T

Switch of the Lowest Excited-States of Terpyridylplatinum(II) Acetylide Complexes Bearing Amino or Azacrown Moieties by Proton and Cations

✍ Qing-Zheng Yang; Qing-Xiao Tong; Li-Zhu Wu; Zi-Xin Wu; Li-Ping Zhang; Chen-Ho Tu 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 172 KB

## Abstract The investigation of the synthesis and unique photophysical properties of two terpyridylplatinum(II) acetylide complexes [Pt(terpy)(C≡CC~6~H~4~‐4‐R)] where terpy is 2,2′:6′,2′′‐terpyridyl and R = N(CH~3~)~2~ (**1**) or __N__‐15‐monoazacrown‐5 (**2**) has been carried out. These complexe