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Excited Biradicals in Thermal Dimerization and Polymerization of Bicyclobutanes

✍ Scribed by K. K. Kalnin'sh; S. G. Semenov


Book ID
106518975
Publisher
SP MAIK Nauka/Interperiodica
Year
2005
Tongue
English
Weight
264 KB
Volume
78
Category
Article
ISSN
1070-4272

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De Mare et al. [13 studied the thermal Diels-Alder dimerization of cyclohexa-1,3-diene (CHD) to endo-dicyclohexadiene and exo-dicyclohexadiene (N and X, respectively) in a static Pyrex system. The temperature ranged from 471 to 639 K and the pressure was varied from 25 tp 630 torr. The formations of