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1,3-Diadamantylallene. Trapping of a biradical intermediate in thermal dimerization of substituted allenes

✍ Scribed by Jacobs, Thomas L.; Kammerer, R. Craig


Book ID
126952622
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
287 KB
Volume
94
Category
Article
ISSN
0002-7863

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De Mare et al. [13 studied the thermal Diels-Alder dimerization of cyclohexa-1,3-diene (CHD) to endo-dicyclohexadiene and exo-dicyclohexadiene (N and X, respectively) in a static Pyrex system. The temperature ranged from 471 to 639 K and the pressure was varied from 25 tp 630 torr. The formations of