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Thermal geometrical isomerization of 1,trans-3,trans-5-heptatriene and the concept of a biradical intermediate

โœ Scribed by Egger, Kurt W.; James, Thomas Ll


Book ID
118177878
Publisher
Royal Society of Chemistry
Year
1970
Weight
854 KB
Volume
66
Category
Article
ISSN
0014-7672

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The Kinetics of the gas-phase isomerizat
โœ Kurt W. Egger; M. Jola ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 694 KB

The kinetics of the nitric oxide catalyzed, homogeneous, gas-phase isomerizatioil of 1 ,trans-3,trans-5-heptatriene have been studied for temperatures ranging between 130ยฐC and 241ยฐC. The very clean reaction involves exclusive geometrical isomerization about the 5,6-x-bond. The observed rate constan