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Exciplexes in supersonic jets

✍ Scribed by Oded Anner; Yehuda Haas


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
155 KB
Volume
40-41
Category
Article
ISSN
0022-2313

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Fluorescence from jet-cooled adduets of styrene and aliphatic amines is reported. Exciplex-type emission is observed from styrene: tertiary amine adduets, as in previous solution work, and from styrene: secondary amines for the first time. The exciplexes are characterized by much longer decay times

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Van der Waals complexes composed of naphthalene and triethylamine have been studied in free jet expansions by fluorescence excitation and resonance-enhanced two-photon ionization techniques. Intermolecular vibrational bands with frequencies of 8 and 40 cm-' appear to promote exciplex formation. The

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Molecular exciplex formation under supersonic jet conditions is studied as a transition from the excited state of the van der Waals complex to a charge-transfer state. For a typical model exciplex system the role of excess excitation energy in the formation process is investigated.