Electronic excitation of the bridged benzenoid hydrocarbon Iepidopterene @.) in the crysWine state and in soiution gives rise to an anomalous luminescence which is attributed to the radiative deactivation of an intramolecular anthraceneethylene exciplex E\*. The formation of E\* and the regeneration
On the role of excitation energy in the formation of a molecular exciplex under supersonic jet conditions
✍ Scribed by I. Deperasinska; J. Prochorow
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 375 KB
- Volume
- 163
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Molecular exciplex formation under supersonic jet conditions is studied as a transition from the excited state of the van der Waals complex to a charge-transfer state. For a typical model exciplex system the role of excess excitation energy in the formation process is investigated.
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The fluorescence of three nearly identical donor-bridge-acceptor molecules was studied under jet-cooled conditions. These compounds contain a I-cyanonaphthalene group as an electron acceptor (A) and an aniline derivative as an electron donor (D). Their only difference is in the substituent on the pa
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## Abstract For Abstract see ChemInform Abstract in Full Text.