Excimer laser photolysis of hexamethyldisilazane
β Scribed by Josef Pola; Roger Taylor
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 380 KB
- Volume
- 446
- Category
- Article
- ISSN
- 0022-328X
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## A new technique IS presented to study translation-to-vibrational (T-V) energytransfer and tradationaiiy enhanced reactive events\_ The method utilizes evcimer laser photobss to produaz transiationalIy "hot" atoms and tirne-resAved in&ared detection of specific exated states\_
Visible luminescence following XeC1 (Eph = 4 eV) and KrF laser (Eph = 5 eV) excitation of Ni(CO)4 is studied in cell and beam experiments. Excitation with yields 4 eV the well-known excited Ni (CO)3 fragment at all pressures and fluences up to 2 J/cm 2. Excitation with 5 eV yields Ni (CO)3 and two n