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Excess isothermal compressibility and excess molar heat capacity of the system benzene + n-heptane

✍ Scribed by S.V. Subrahmanyam; K. Raghunath


Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
136 KB
Volume
2
Category
Article
ISSN
0009-2614

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πŸ“œ SIMILAR VOLUMES


Excess molar volumes and excess molar he
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Excess molar volumes were determined over the whole composition range for (dimethyl carbonate, or diethyl carbonate + n-heptane) at the temperatures (278.15, 288.15, 298.15, and 308.15) K, and at atmospheric pressure with a vibrating-tube densimeter. In addition, a differential scanning calorimeter

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Excess molar enthalpies and excess molar heat capacities at T = 298.15 K were determined for {xCHCl3 Both experimental properties were represented by a Redlich-Kister type equation. The large negative values of the excess enthalpies and the positive values of the excess heat capacities observed in

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## Ž . Ž . 4 x c-CH O q 1 y x y x c-C H . The experimental data were described through a 2 24 1 2 6 1 2 Redlich᎐Kister type equation. The ternary mixtures exhibit large positive deviations for both properties investigated. Ternary H E and C E data were poorly predicted by rules which m p, m empiri